higgy wrote:pure bullshit,You are confused.

Boyles law rules. pvt1 = pvt2 period. Increasing the temperature or the pressure on the fuel makes it burn faster( at a higher flame propagation)Detonation or its cousin pinging is as you state due to instant combustion brought on by either higher pressure or higher temperature than the octane of the fuel is rated for.Detonation is way to fast burning,charge ignites while the piston is still moving up btdc,all at once,pinging is too fast burning,burns faster than the piston can accelerate down but atdc. Newer Ducati use compression ratios of 11:1 or higher and as I stated if your compression ratio is over 10.5 :1 you need a higher octane. Higher octane fuels by definition burn slower,at a slower flame propagation than low octane fuels.modifications to cylinder heads are designed to raise compression by increasing the break mean effective pressure of the charge entering the cylinder effectively doing the same thing as decreasing the volume of the combustion chamber( raising the compression ratio) bigger charge more pressure,more heat more power.
by the way if you put someone who is 200 lbs on the same engine as someone who is 100 lbs,you increase the compression . If you ride into the wind you increase the compression , if you tow you increase the compression .If you ride uphill you increase the compression .But the ratio stays the same.
It is all about pressure,temperature and volume.
Two plugs,two flame fronts propagating burning the complete charge faster not faster flame propagation
Also 87 octane fuel has no more or less energy than 89 or 91 octane fuels.energy output is the same regardless of octane rating
The noise you hear in either case of pinging or detonation is your piston forcing the rod into the crankshaft and in the worst case all of the above shattering from pressure that exceeds their design.
rant off................

Well NOW I'm confused, that's certain. Help me out - which term of Boyle's Law represents the fuel mixture burning?
There is NOTHING in Boyles law that has anything to do with a fuel burning. It doesn't take combustion into account. I'm confused why you brought a formula that doesn't apply to combustion into a post about flame speed?
Higher octane fuels BY DEFINITION burn slower? I'm confused by that. Post a defintion of octane rating from any tech site that puts burn rate in the definition so I can see what I've been missing all these years.
I'm confused why you talk about static and dynamic compression. So what? I never mentioned that. I never said anything about power output or octane requirements, I simply said higher octane gasoline does not control knock by burning slower. And it doesn't. (Oops, I just reread my post and what I really said was it doesn't burn slower.)
And THIS has me really confused:
Two plugs,two flame fronts propagating burning the complete charge faster not faster flame propagation
My confusion lies in that it seems like you are implying it's ok to have the mixture burn in X amount of time because of turblulence, but not ok to have it burn in X amount of time because of the flame speed itself. The mixture is getting burned in the same amount of time... assuming you aren't requiring the flame speed to go supersonic I'm missing how the pressure/temp profiles will be different between the two cases. This amount of fuel in this amount of time either way. And it's all about pressure and temp, you said so yourself. Oh wait, you added volume. I'm confused on how a different volume at the same temp and pressure will matter. Put the mix in a 45cc chamber at a given temp and pressure or a 50cc chamber at the given temp and pressure, the mix will still have the same delay before it auto-ignites. The chemistry relies on the temp and pressure, not the volume.
And yes, the damage caused by detonation is due to shock waves, not by "pressure that exceeds their design". The shock wave does cause pressure spikes for sure, it's the spikes that do the damage. The spike destroys the boundry layer which protects the piston from the heat of combustion, overheating the part. And then the pressure spikes hammer the surface of the piston/head. The pressure doesn't simply squeeze it until something shatters.
FWIW If what I've posted is bullshit, you might want to get in touch with the people at Crane Cams and Shell Oil company, plus the publishers of every text on engine theory I've ever seen.
From Shell Oil:
http://www.shell.com/home/Framework?sit ... _2101.html
Q: How is the octane rating determined?
A: The octane rating specifies the knock resistance of the carburettor fiel. Isooctane, which is defined as having an octane rating of 100 and n-heptane, which has a defined octane rating of 0, are used as a comparison mix to determine the octane rating. Octane ratings are determined in CFR test engines, which are standard world-wide.
[Hmm, no mention of flame speed in Shell's definition...]
Crane Cams knows a little about this stuff I would hope:
http://www.cranecams.com/?show=newsLetters&no=119
Playing ?The Octane Game?, Or. . . Is ?Race Gas? The Same Stuff As ?Av-Gas??
Many racers mistakenly believe that octane is the most important factor in selecting a fuel for racing. They think that the higher the octane number, the more power a fuel will provide. This is misguided thinking which totally ignores the most critical feature of a racing fuel - flame speed at a given cylinder pressure.
Octane number only measures a fuel?s resistance to detonation and pre-ignition. It does not have any direct relationship to flame speed, which is critical to maximizing cylinder pressure (horsepower).
Racing fuels are designed to maximize flame speeds at high cylinder pressures typical of competition and/or supercharged engines. They are also designed for high engine speeds (above 5,000 RPM). By contrast, aviation gasoline is designed for relatively low compression engines operating in the 2,700 ? 2,800 RPM range at 8,000 to 10,000 ft. altitude. Quite different from a racing engine! Compared to racing fuel, the transient response (measure of an engine?s ?throttle response;? the ability to rev quickly) of aviation fuel is poor. This is a result of the blend of the gasoline and is no way measured by octane rating. Unfortunately, there is no quick and easy way to measure the various types of racing fuel, and don?t assume that the highest octane is the quickest fuel.
The people at Shell Oil company seem to disagree with the the defined relationship between octane rating and flame speed. Ease my confusion. Explain where they're wrong.
And not that an astonomy site is an obvious source but it shows up and was interesting.
http://www.absoluteastronomy.com/topics/Octane_rating
Unfortunately the site doesn't copy/paste well so you'll have to check it out for yourself.
Not sure who Thor racing is but this is what their site says
http://www.thor-racing.co.uk/Octane_Rating-149.asp
What fuel property does the Octane Rating measure?
The fuel property the octane ratings measure is the ability of the unburnt end gases to spontaneously ignite under the specified test conditions. Within the chemical structure of the fuel is the ability to withstand pre-flame conditions without decomposing into species that will autoignite before the flame-front arrives. Different reaction mechanisms, occurring at various stages of the pre-flame compression stroke, are responsible for the undesirable, easily-autoignitable, end gases.
During the oxidation of a hydrocarbon fuel, the hydrogen atoms are removed one at a time from the molecule by reactions with small radical species (such as OH and HO2), and O and H atoms. The strength of carbon-hydrogen bonds depends on what the carbon is connected to. Straight chain HCs such as normal heptane have secondary C-H bonds that are significantly weaker than the primary C-H bonds present in branched chain HCs like iso-octane.
The octane rating of hydrocarbons is determined by the structure of the molecule, with long, straight hydrocarbon chains producing large amounts of easily-autoignitable pre-flame decomposition species, while branched and aromatic hydrocarbons are more resistant. This also explains why the octane ratings of paraffins consistently decrease with carbon number. In real life, the unburnt "end gases" ahead of the flame front encounter temperatures up to about 700C due to compression and radiant and conductive heating, and commence a series of pre-flame reactions. These reactions occur at different thermal stages, with the initial stage (below 400C) commencing with the addition of molecular oxygen to alkyl radicals, followed by the internal transfer of hydrogen atoms within the new radical to form an unsaturated, oxygen-containing species. These new species are susceptible to chain branching involving the HO2 radical during the intermediate temperature stage (400-600C), mainly through the production of OH radicals. Above 600C, the most important reaction that produces chain branching is the reaction of one hydrogen atom radical with molecular oxygen to form O and OH radicals.
The addition of additives such as alkyl lead and oxygenates can significantly affect the pre-flame reaction pathways. Antiknock additives work by interfering at different points in the pre-flame reactions, with the oxygenates retarding undesirable low temperature reactions, and the alkyl lead compounds react in the intermediate temperature region to deactivate the major undesirable chain branching sequence.
The antiknock ability is related to the "autoignition temperature" of the hydrocarbons.
Antiknock ability is _not_ substantially related to:-
1. The energy content of fuel, this should be obvious, as oxygenates have lower energy contents, but high octanes.
2.
The flame speed of the conventionally ignited mixture, this should be evident from the similarities of the two reference hydrocarbons. Although flame speed does play a minor part, there are many other factors that are far more important. ( such as compression ratio, stoichiometry, combustion chamber shape, chemical structure of the fuel, presence of antiknock additives, number and position of spark plugs, turbulence etc.)
Flame speed does not correlate with octane.
My "pure bullshit" is supported by any number of sources. And yes, I know you can find sources on the 'net to support any claim. I tried to stick with more reputable ones here but I don't really have time to wade through everything at work - these were handy from a simple Google search. I suppose I could dig out my old texts. They're all about 25 years old now but I doubt the physics has changed much. That said, I'd be happy to see more current sources you have if you care to post them.